- Raw materials
Primary precursors:
- a) 2,5-Dimethylaniline (C8H11N)
- b) Succinic acid (C4H6O4) or succinic anhydride (C4H4O3)
Secondary reagents and catalysts:
- a) Polyphosphoric acid (PPA) as condensing agent and solvent
- b) Sodium nitrite (NaNO2) for diazotization
- c) Copper(I) chloride (CuCl) as catalyst for cyclization
Solvents and processing aids:
- a) N-Methylpyrrolidone (NMP) for purification
- b) Methanol for precipitation and washing
- Synthesis process
Condensation reaction:
- a) 2,5-Dimethylaniline reacts with succinic acid in PPA at 80-100°C
- b) Formation of 2,5-diarylaminoterephthalic acid intermediate
- c) Reaction time: 4-6 hours under controlled stirring
Ring closure:
- a) Temperature increase to 150-180°C
- b) Intramolecular cyclization to form quinacridone structure
- c) Duration: 2-4 hours with careful temperature control
Oxidation:
- a) Addition of sodium nitrite at 80-90°C
- b) Oxidation of leuco quinacridone to final quinacridone pigment
- c) Reaction time: 1-2 hours with precise pH control (pH 1-2)
Crystal phase control:
- a) Heating in high-boiling solvent (e.g., N-methylpyrrolidone) at 200-220°C
- b) Conversion to γ-phase crystal modification
- c) Duration: 2-4 hours under reflux conditions
- Purification methods
Filtration and washing:
- a) Hot filtration to separate crude pigment
- b) Multiple washing steps with water and methanol
- c) Acid treatment to remove metal impurities
Solvent treatment:
- a) Extraction with NMP to remove organic impurities
- b) Reprecipitation by addition to cold water
Milling and classification:
- a) Wet milling to achieve desired particle size distribution
- b) Classification using hydrocyclones or centrifuges
- D. Post-synthesis treatments
Surface treatment:
- a) Application of surfactants or resins to improve dispersibility
- b) Typical agents: Fatty acid derivatives, polyethylene glycols
Particle size adjustment:
- a) Jet milling for ultra-fine particles
- b) Controlled aggregation for specific applications
Applications
- Coatings and paints
Automotive finishes
- a) High-end metallic and pearlescent finishes
- b) Clear coat systems for enhanced durability
- c) Color-shifting effects when combined with interference pigments
Industrial coatings
- a) Heavy machinery and equipment coatings
- b) Appliance finishes
- c) Aerospace coatings for both exterior and interior applications
Architectural paints
- a) Premium interior wall paints
- b) Exterior facade coatings with high weather resistance
- c) Wood stains and varnishes for decorative purposes
- Plastics coloration
Engineering plastics
- a) Polyamides (PA) for automotive components
- b) Polyoxymethylene (POM) for precision parts
- c) Polycarbonate (PC) for electronic housings
Consumer goods
- a) Household appliances and kitchenware
- b) Toys and sporting goods
- c) Personal care product packaging
- Printing inks
Packaging inks
- a) Flexographic inks for flexible packaging
- b) Gravure inks for high-quality packaging
- c) UV-curable inks for specialty packaging
Publication inks
- a) Sheet-fed offset inks for high-end magazines
- b) Heat-set web offset inks for catalogs and brochures
Security printing
- a) Banknote inks
- b) Anti-counterfeiting features in official documents
- Artists’ colors
Oil paints for fine art
Acrylic paints for both professional and hobby use
Watercolors and gouache
Colored pencils and pastels
- Textile printing and dyeing
Direct printing on natural and synthetic fabrics
Dye sublimation printing for polyester fabrics
Pigment dyeing for denim and other heavy fabrics
- Cosmetics and personal care products
Nail polishes and nail art products
Eye shadows and other color cosmetics
Hair dyes and temporary hair color products
- Emerging applications
Solar cells
- a) Organic photovoltaics as a sensitizer
- b) Dye-sensitized solar cells (DSSCs) for improved light absorption
Organic electronics
- a) Organic light-emitting diodes (OLEDs) for displays
- b) Organic field-effect transistors (OFETs)
Biomedical applications
- a) Fluorescent markers for cellular imaging
- b) Photodynamic therapy agents
- Specialty papers and cardboards
High-quality gift wrapping papers
Luxury packaging papers
Artist-grade colored papers
- Ceramics and glass coloration
Ceramic glazes for decorative tiles
Glass enamels for architectural glass
Colored glass for art and decoration
- 3D printing materials
Colorants for ABS and PLA filaments
Pigments for SLA and DLP resins
Color agents for powder-based 3D printing
- Rubber and elastomer coloration
Colored rubber flooring
Automotive rubber components
Sporting goods (e.g., yoga mats, exercise bands)
- Concrete and construction materials
Colored concrete for decorative applications
Pigmented grouts and mortars
Coloration of synthetic stones
- Functional coatings
Anti-corrosion coatings with color-indicating properties
Heat-reflective coatings for energy efficiency
Antimicrobial coatings with aesthetic appeal
- Digital printing
Inkjet inks for large format printing
Toners for digital laser printers
Dye-sublimation printing for textiles and hard surfaces
- Color filters
LCD displays
Optical filters for scientific instruments
Lighting gels for stage and film production
Performance Characteristics
- Color strength and brilliance
Tinting strength
- a) High tinting strength with a tinting strength index of 115-125 compared to standard
- b) Excellent color development in various media
- c) Ability to achieve deep shades with relatively low pigment loading
Masstone characteristics
- a) Rich, vibrant violet color in full strength applications
- b) Slight reddish undertone contributing to its unique shade
Undertone properties
- a) Clean, slightly bluish undertone in tint reductions
- b) Consistent undertone across different application media
Chroma and saturation
- a) High chroma values, typically 70-75 in CIELAB color space
- b) Excellent color saturation, maintaining vibrancy even in deep shades
- Dispersibility in various media
Organic solvents
- a) Excellent dispersibility in polar organic solvents
- b) Moderate dispersibility in non-polar solvents, may require dispersing agents
Water-based systems
- a) Good dispersibility in water with appropriate surfactants
- b) Stable dispersion in aqueous coating formulations
Polymers and resins
- a) High compatibility with a wide range of polymer systems
- b) Easy incorporation into thermoplastics and thermosets
Dispersion stability
- a) Low tendency for flocculation in properly dispersed systems
- b) Minimal color float and good color consistency
- Heat resistance
Thermal stability
- a) Excellent color stability up to 280-300°C in most polymer systems
- b) Minimal color shift at elevated temperatures
Processing stability
- a) Withstands high-temperature processing in plastics (e.g., injection molding)
- b) Suitable for high-temperature cure coatings
- Chemical resistance
Acid resistance
- a) Excellent stability in acidic environments (pH 2-7)
- b) Minimal color change or degradation in presence of weak to moderate acids
Alkali resistance
- a) Good stability in alkaline conditions (pH 7-12)
- b) Slight color shift may occur in strongly alkaline environments
Solvent resistance
- a) High resistance to common organic solvents
- b) Excellent bleed resistance in solvent-based systems
Oxidation and reduction resistance
- a) Good stability against oxidizing agents
- b) Moderate resistance to strong reducing agents
- Opacity/transparency
Opacity in full shade
- a) Medium to high opacity in masstone applications
- b) Hiding power increases with pigment concentration
Transparency in tints
- a) Good transparency in tint reductions
- b) Suitable for transparent effect finishes and glazes
Influence of particle size
- a) Finer particle sizes increase transparency
- b) Larger particles or aggregates enhance opacity
- Lightfastness and weatherability
Lightfastness
- a) Excellent lightfastness (8/8 on the Blue Wool Scale)
- b) Minimal fading under prolonged exposure to UV light
Weatherability
- a) Outstanding weather resistance (typically 5/5 on standard scales)
- b) Excellent retention of color and gloss in exterior applications
UV stability
- a) High resistance to UV-induced degradation
- b) Minimal chalking or color change in outdoor exposures